K. Emma Knowland

and 15 more

The NASA Goddard Earth Observing System (GEOS) Composition Forecast (GEOS-CF) provides recent estimates and five-day forecasts of atmospheric composition to the public in near-real time. To do this, the GEOS Earth system model is coupled with the GEOS-Chem tropospheric-stratospheric unified chemistry extension (UCX) to represent composition from the surface to the top of the GEOS atmosphere (0.01 hPa). The GEOS-CF system is described, including updates made to the GEOS-Chem UCX mechanism within GEOS-CF for improved representation of stratospheric chemistry. Comparisons are made against balloon, lidar and satellite observations for stratospheric composition, including measurements of ozone (O3) and important nitrogen and chlorine species related to stratospheric O3 recovery. The GEOS-CF nudges the stratospheric O3 towards the GEOS Forward Processing (GEOS FP) assimilated O3 product; as a result the stratospheric O3 in the GEOS-CF historical estimate agrees well with observations. During abnormal dynamical and chemical environments such as the 2020 polar vortexes, the GEOS-CF O3 forecasts are more realistic than GEOS FP O3 forecasts because of the inclusion of the complex GEOS-Chem UCX chemistry. Overall, the spatial pattern of the GEOS-CF simulated concentrations of stratospheric composition agrees well with satellite observations. However, there are notable biases – such as low NOx and HNO3 in the polar regions and generally low HCl throughout the stratosphere – and future improvements to the chemistry mechanism and emissions are discussed. GEOS-CF is a new tool for the research community and instrument teams observing trace gases in the stratosphere and troposphere, providing near-real-time three-dimensional gridded information on atmospheric composition.

H. J. Ray Wang

and 18 more

The Stratospheric Aerosol and Gas Experiment III on the International Space Station (SAGE III/ISS) was launched on February 19, 2017 and began routine operation in June 2017. The first two years of SAGE III/ISS (v5.1) solar ozone data were evaluated by using correlative satellite and ground-based measurements. Among the three (MES, AO3, and MLR) SAGE III/ISS solar ozone products, AO3 ozone shows the best accuracy and precision, with mean biases less than 5% for altitudes ~15–55 km in the mid-latitudes and ~20–55 km in the tropics. In the lower stratosphere and upper troposphere, AO3 ozone shows high biases that increase with decreasing altitudes and reach ~10% near the tropopause. Preliminary studies indicate that those high biases primarily result from the contributions of the oxygen dimer (O) not being appropriately removed within the ozone channel. The precision of AO3 ozone is estimated to be ~3% for altitudes between 20 and 40 km. It degrades to ~10–15% in the lower mesosphere (~55 km), and ~20–30% near the tropopause. There could be an altitude registration error of ~100 meter in the SAGE III/ISS auxiliary temperature and pressure profiles. This, however, does not affect retrieved ozone profiles in native number density on geometric altitude coordinates. In the upper stratosphere and lower mesosphere (~40–55 km) the SAGE III/ISS (and SAGE II) sunset ozone values are systematically higher than sunrise data by ~5–8% which are almost twice larger than what observed by other satellites or model predictions. This feature needs further study.