Multispectral mapping data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) provide a unique opportunity to characterize south polar ice deposits at higher spectral sampling, spatial resolution, or spatiotemporal coverage than previous work. This new perspective can help to constrain the nature and distribution of different mixtures of CO2 ice, H2O ice, and dust that influence the formation, evolution, and preservation of Mars climate records. We processed 1103 CRISM observations spanning southern summer of six Mars Years (MY) through a combination of k-means clustering and random forest classification. Using a set of 12 spectral endmembers directly tied to previous work with high-resolution CRISM targeted data, we made a series of temporally restricted mosaics showing surface spectral variation over time. The mosaics show the effects of the MY 28 dust storm on the removal of the seasonal CO2 ice cap that year and reveal how this process differed from the years that followed. A mosaic showing residual ice surfaces displays broad agreement with previous compositional maps while resolving new details in the distribution of H2O ice-rich material around the periphery of the bright CO2 ice cap. By showing how surface composition varies across a broad swath of the south polar region though time, the endmember set and classified mosaics produced in this work can provide critical context for future studies of the dynamic processes that shape south polar ice deposits.

Jezero crater, an ancient lake basin that is the landing site of the Mars 2020 Perseverance rover, contains a carbonate-bearing rock unit termed the margin fractured unit. Some of the carbonates in these rocks may have formed in a fluviolacustrine environment and therefore could preserve biosignatures of paleolake-inhabiting lifeforms. Here we evaluate whether these margin fractured unit carbonates formed as authigenic precipitates in a fluviolacustrine environment or via alteration of primary minerals by groundwater. We integrate thermal inertia measurements from the Thermal Emission Imaging System (THEMIS), spectral analyses from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM), examination of stratigraphic relationships in Jezero crater using High Resolution Science Experiment (HiRISE) and Context Camera (CTX) images and digital elevation models. We also compare the Jezero crater results to observations from the Curiosity rover in Gale crater. We find that margin fractured bedrock with the deepest visible-to-near-infrared carbonate absorptions also has exceptionally high thermal inertia and thickness relative to other carbonate-bearing units in Jezero crater, consistent with enhanced cementation and crystallization by groundwater. Our results indicate that it is equally likely that carbonates in Jezero crater formed via alteration of primary minerals by alkaline groundwater rather than as authigenic precipitates in a fluviolacustrine environment. Jezero crater may have hosted ancient subsurface habitable environments related to these groundwaters, where life-sustaining redox energy was generated by water-rock interactions. The Mars 2020 Perseverance rover could encounter biosignatures preserved from this carbonate-forming environment, whether it was fluviolacustrine or in the subsurface.