Michelle L. Santee

and 9 more

The January 2022 eruption of Hunga Tonga-Hunga Ha’apai (HT-HH) caused the largest enhancement in stratospheric aerosol loading in decades and produced an unprecedented enhancement in stratospheric water vapor, which led to strong stratospheric cooling that in turn induced changes in the large-scale circulation. Here we use satellite measurements of gas-phase constituents together with aerosol extinction to investigate the extent to which the thick aerosol, excess moisture, and strong cooling enabled heterogeneous chemical processing. In the southern tropics, unambiguous signatures of substantial chlorine and nitrogen repartitioning appear over a broad vertical domain almost immediately after the eruption, with depletion of N2O5, NOx, and HCl accompanied by enhancement of HNO3, ClO, and ClONO2. After initially rising steeply, HNO3 and ClO plateau, maintaining fairly constant abundances for several months. These patterns are consistent with the saturation of N2O5 hydrolysis, suggesting that this reaction is the primary mechanism for the observed composition changes. The southern midlatitudes and subtropics show similar but weaker enhancements in ClO and ClONO2. In those regions, however, effects of anomalous transport dominate the evolution of HNO3 and HCl, obscuring the signs of heterogeneous processing. Perturbations in chlorine species are considerably weaker than those measured in the southern midlatitude stratosphere following the Australian New Year’s fires in 2020. The moderate HT-HH-induced enhancements in reactive chlorine seen throughout the southern middle and low-latitude stratosphere, far smaller than those in typical winter polar vortices, do not lead to appreciable chemical ozone loss; rather, extrapolar lower-stratospheric ozone remains primarily controlled by dynamical processes.

Eun-Pa Lim

and 11 more

In the austral spring seasons of 2020-2022, the Antarctic stratosphere experienced three consecutive strong vortex events. In particular, the Antarctic vortex of October-December 2020 was the strongest on record in the satellite era for that season at 60°S in the mid- to lower stratosphere. However, it was poorly predicted by the Australian Bureau of Meteorology’s operational seasonal climate forecast system of that time, ACCESS-S1, even at a short lead time of a month. Using the current operational forecast system, ACCESS-S2, we have, therefore, tried to find a primary cause of the limited predictability of this event and conducted forecast sensitivity experiments to climatological versus observation-based ozone to understand the potential role of the ozone forcing in the strong vortex event and associated anomalies of the Southern Annular Mode (SAM) and south-eastern Australian rainfall. Here, we show that the 2020 strong vortex event did not follow the canonical dynamical evolution seen in previous strong vortex events in spring, whereas the ACCESS-S2 control forecasts with the climatological ozone did, which likely accounts for the inaccurate forecasts of ACCESS-S1/S2 at 1-month lead time. Forcing ACCESS-S2 with observed ozone significantly improved the skill in predicting the strong vortex in October-December 2020 and the subsequent positive SAM and related rainfall increase over south-eastern Australia in the summer of December 2020 to February 2021. These results highlight an important role of ozone variations in seasonal climate forecasting as a source of long-lead predictability, and therefore, a need for improved ozone forcing in future ACCESS-S development.

Michelle L. Santee

and 8 more

The 2022 Hunga eruption led to extraordinary water vapor enhancement throughout the stratospheric vortex at the beginning of the 2023 Antarctic winter. Although the dynamical characteristics of the vortex itself were generally unexceptional, the excess moisture initially raised the threshold temperatures for the formation of polar stratospheric clouds (PSCs) above typical values over a broad vertical domain. Low temperatures, especially during an early-July cold spell, prompted ice PSC formation and unusually severe irreversible dehydration at higher levels (500–700 K), while atypical rehydration occurred at lower levels (380–460 K). Heterogeneous chemical processing was more extensive, both vertically (up to 750–800 K) and temporally (earlier in the season), than in prior Antarctic winters. The resultant HCl depletion and ClO enhancement both redefined their previously observed ranges at and above 600 K. Albeit unmatched in the satellite record, the early-winter upper-level chlorine activation was insufficient to induce substantial ozone loss. Chlorine activation, denitrification, and dehydration processes saturated in midwinter, with trace gas evolution essentially following the climatological mean thereafter. Chlorine deactivation started slightly later than in most years. While cumulative ozone losses at 410–550 K were relatively large, probably because of the delayed chlorine deactivation, they were not unprecedented. Thus, ozone depletion was unremarkable throughout the lower stratosphere. Although Hunga hastened the onset of and increased the vertical extent of PSC formation and chlorine activation in early winter, saturation of lower stratospheric chemical processing (as is typical in the Antarctic) prevented an exceptionally severe ozone hole in 2023.

Kristof Bognar

and 17 more

In the winter and spring of 2019/2020, the unusually cold, strong, and stable polar vortex created favorable conditions for ozone depletion in the Arctic. Chemical ozone loss started earlier than in any previous year in the satellite era, and continued until the end of March, resulting in the unprecedented reduction of the ozone column. The vortex was located above the Polar Environment Atmospheric Research Laboratory in Eureka, Canada (80 °N, 86 °W) from late February to the end of April, presenting an excellent opportunity to examine ozone loss from a single ground station. Measurements from a suite of instruments show that total column ozone in 2020 was at an all-time low in the 20-year dataset, 22 to 102 DU below previous records set in 2011. Ozone minima (<200 DU), enhanced OClO and BrO slant columns, and unusually low HCl, ClONO2 , and HNO3 columns were observed in March. Polar stratospheric clouds were present as late as 20 March, and ozonesondes show unprecedented depletion in the March and April ozone profiles (to <0.2 ppmv). While both chemical and dynamical factors lead to reduced ozone when the vortex is cold, the contribution of chemical depletion was exceptional in spring 2020 when compared to typical Arctic winters. The mean chemical ozone loss over Eureka was estimated to be 111-127 DU (27-31%) using April measurements and passive ozone from the SLIMCAT chemical transport model. While absolute ozone loss was generally smaller in 2020 than in 2011, percentage ozone loss was greater in 2020.

Krzysztof Wargan

and 6 more

MERRA-2 Stratospheric Composition Reanalysis of Aura Microwave Limb Sounder (M2-SCREAM) is a new reanalysis of stratospheric ozone, water vapor, hydrogen chloride (HCl), nitric acid (HNO3) and nitrous oxide (N2O) between 2004 and the present (with a latency of several months). The assimilated fields are provided at a 50-km horizontal resolution and at a three-hourly frequency. M2-SCREAM assimilates version 4.2 Microwave Limb Sounder (MLS) profiles of the five constituents alongside total ozone column from the Ozone Monitoring Instrument. Dynamics and tropospheric water vapor are constrained by the MERRA-2 reanalysis. The assimilated species are in excellent agreement with the MLS observations, except for HNO3 in polar night, where data are not assimilated. Comparisons against independent observations show that the reanalysis realistically captures the spatial and temporal variability of all the assimilated constituents. In particular, the standard deviations of the differences between M2-SCREAM and constituent mixing ratio data from The Atmospheric Chemistry Experiment Fourier Transform Spectrometer are much smaller than the standard deviations of the measured constituents. Evaluation of the reanalysis against aircraft data and balloon-borne frost point hygrometers indicates a faithful representation of small-scale structures in the assimilated water vapor, HNO3 and ozone fields near the tropopause. Comparisons with independent observations and a process-based analysis of the consistency of the assimilated constituent fields with the MERRA-2 dynamics and with large-scale stratospheric processes demonstrate the utility of M2-SCREAM for scientific studies of chemical and transport variability on time scales ranging from hours to decades. Analysis uncertainties and guidelines for data usage are provided.

Gloria L Manney

and 3 more