Micheline Campbell

and 7 more

Understanding past fire regimes and how they vary with climate, human activity, and vegetation patterns is fundamental to the mitigation and management of changing fire regimes as anthropogenic climate change progresses. Ash-derived trace elements and pyrogenic biomarkers from speleothems have recently been shown to record past fire activity in speleothems from both Australia and North America. This calls for an empirical study of ash geochemistry to aid the interpretation of speleothem palaeofire proxy records. Here we present analyses of leached ashes collected following fires in southwest and southeast Australia. We include a suite of inorganic elemental data from the water-soluble fraction of ash, as well as a selection of organic analytes (pyrogenic lipid biomarkers). We also present elemental data from leachates of soils collected from sites in southwest Australia. We demonstrate that the water-soluble fraction of ash differs from the water-soluble fraction of soils, with trace and minor element concentrations in ash leachates varying with combustion completeness (burn severity) and sample location. Changes in some lipid biomarker concentrations extracted from ashes may reflect burn severity. Our results contribute to building a process-based understanding of how speleothem geochemistry may record fire frequency and severity, and suggest that more research is needed to understand the transport pathways for the inclusion of pyrogenic biomarkers in speleothems. Our results also demonstrate that potential contaminant loads from ashes are much higher than from soils, with implications for the management of karst catchments, which are a critical water resource.

Andy Baker

and 3 more

In water-limited environments, quantifying the timing and frequency of erratic rainfall recharge events and its climate forcing is of critical importance for groundwater resource management. In temperate semi-arid New South Wales, SE Australia (precipitation: 615 mm/year, pan evaporation: 1679 mm/year), since 2010 we have been using a limestone cave situated at 20 m below land surface, and just above the water table, as a vadose zone observatory of potential recharge approximated by drip rate observations. Complimented since 2018 by a soil moisture probe network and using the VarKarst karst-specialized recharge model, we investigate the climatic, hydrological and karst geological controls on recharge dynamics. We observe nineteen recharge events (07.2010 to 01.2021). They cluster into two periods (1) seven events between 08.2010 and 12.2010 during a La Niña (enhanced spring rainfall is typical in eastern Australia) and (2) seven events between 06.2016 and 10.2016 associated with a negative Indian Ocean Dipole (which is associated with wet winters and springs in southern Australia). Comparison with antecedent rainfall indicates a minimum of 40 mm rainfall over 14-days is required for recharge in winter, and >120 mm rainfall over 14-days in summer. We will use the karst recharge model to simulate the observed recharge events and to quantify the threshold behavior of the soil and vadose zone above the cave. Two recharge events have occurred since the establishment of the soil moisture network (03.05.2020, 29.07.2020). For those, we can analyze the influence of antecedent soil storage on the initiation of recharge and use this understanding for an evaluation of the simulated internal fluxes and storages of karst recharge model. Providing realistic results of both recharge and soil moisture observations, the model can be used as tool to predict the impact of past and future climate changes on groundwater renewal.

Micheline Campbell

and 7 more

Wildfires affect 40% of the earth’s terrestrial biome, but much of our knowledge of wildfire activity is limited to the satellite era. Improved understanding of past fires is necessary to better understand how wildfires might change with future climate change, to understand ecosystem resilience, and to improve data-model comparisons. Environmental proxy archives can extend our knowledge of past fire activity. Speleothems, naturally occurring cave formations, are widely used in palaeoenvironmental research as they are absolutely dateable, occur on every ice-free continent, and include multiple proxies. Recently, speleothems have been shown to record past fire events (McDonough et al., 2022). Here we present a review of this emerging application in speleothem palaeoenvironmental science. We give a concise overview of fire regimes and traditional palaeofire proxies, describe past attempts to use stalagmites to investigate palaeofire, and describe the physical basis though which speleothems can record past fires. We then describe the ideal speleothem sample for palaeofire research and offer a summary of applicable laboratory and statistical methods. Finally, we present four case studies which detail [1] the geochemistry of ash leachates, [2] how sulphur may be a proxy for post fire ecological recovery, [3] how a catastrophic palaeofire was linked to changes in climate and land management, and [4] demonstrate that deep caves can record past fire events. We conclude the paper by suggesting that speleothem δ18O research may need to consider the impact of fire on δ18O values, and outline future research directions.
My earth science focused PhD research included the analysis of annual fluorescent laminae in cave stalagmites, under the supervision of karst hydrologist Peter Smart (Bristol, UK). At the time, the source of this fluorescence was uncertain, opening new research opportunities characterizing what is now understood to be soil-derived, water-soluble fluorescent dissolved and colloidal organic matter that is transported to the cave by vadose zone percolation waters. Aquatic organic matter fluorescence research benefitted at this time from significant laboratory analytical advances that were commercially driven, including Sony’s Blu-ray technology and the use of fluorescent labelling in the biomedical sciences. Faster analyses at increasingly higher energy excitation energies opened opportunities for novel fingerprinting of organic matter in hydrological science, including landfill leachates and sewage contamination. Today, hand-held fluorescence sensors can instantaneously determine microbial water quality. And back in the field of speleothem (cave deposit) science, annual geochemical laminae are now recognized to be widely preserved in regions where there is a seasonality in recharge, providing a precise chronology for the stalagmite paleoenvironmental archive. Currently, we are utilizing this precise chronology to generate high-resolution fire history records, where the fire proxy is water-soluble ash-derived elements transported from soil to cave by vadose zone percolation waters.