Samples
|
λFmax
(nm)
|
τF
(ns)
|
ФF+P
(%)
|
ФF
(%)
|
aKrF
(107s-1)
|
bKisc
(107s-1)
|
λpmax
(nm)
|
τP
(s)
|
cФP
(%)
|
dKrP
(10-2s-1)
|
eKnrP
(s-1)
|
PPh3
|
432 |
4.15 |
2.86 |
2.55 |
0.61 |
0.07 |
521 |
0.08 |
0.31 |
3.88 |
12.46 |
5-TAT-OMe/PPh3
|
411 |
4.64 |
27.24 |
19.93 |
4.30 |
1.58 |
499 |
0.70 |
7.31 |
10.44 |
1.32 |
5-TAT-H/PPh3
|
409 |
3.66 |
20.36 |
15.70 |
4.29 |
1.27 |
538 |
0.99 |
4.66 |
4.71 |
0.96 |
5-TAT-CN/PPh3
|
461 |
3.26 |
37.40 |
24.44 |
7.50 |
3.98 |
524 |
0.51 |
12.96 |
25.41 |
1.71 |
6-TAT-OMe/PPh3
|
430 |
4.28 |
24.28 |
16.56 |
3.87 |
1.80 |
536 |
0.90 |
7.72 |
8.58 |
1.03 |
6-TAT-H/PPh3
|
429 |
4.45 |
36.39 |
24.48 |
5.50 |
2.68 |
536 |
0.97 |
11.91 |
12.28 |
0.91 |
6-TAT-CN/PPh3
|
492 |
2.77 |
47.31 |
17.96 |
6.48 |
10.60 |
528 |
0.76 |
29.35 |
38.62 |
0.93 |