Dolomite (CaMg(CO3)2) forms in minor quantities in modern environments yet comprises most of the Precambrian carbonate rock record. Precambrian dolomites are often fine-grained and fabric-retentive and are interpreted to have precipitated as primary cements or formed as early diagenetic replacements of CaCO3. Detailed physical and chemical characterization of these dolomites could inform their origin and relevance for paleoenvironmental reconstruction. Here, we use synchrotron radiation to produce a nanometer-resolution crystal orientation map of one exquisitely-preserved ooid deposited at the onset of the Shuram carbon isotope excursion (~574 Ma). The crystal orientation map reveals small (~10μm) acicular, radially-oriented crystals grouped into bundles of similarly-oriented crystals with varying optical properties. We interpret that this dolomite formed via primary, spherulitic precipitation during ooid growth in shallow marine waters. This result provides additional evidence that the physicochemical properties of late Precambrian oceans promoted dolomite precipitation and supports a primary origin for the Shuram excursion.

Inequalities persist in the geosciences. White women and people of color remain under-represented at all levels of academic faculty, including positions of power such as departmental and institutional leadership. While the proportion of women among geoscience faculty has been catalogued previously, new programs and initiatives aimed at improving diversity, focused on institutional factors that affect equity in the geosciences, necessitate an updated study and a new metric for quantifying the biases that result in under-representation . We compile a dataset of 2,531 tenured and tenure-track geoscience faculty from 62 universities in the United States to evaluate the proportion of women by rank and discipline. We find that 27% of faculty are women. The fraction of women in the faculty pool decreases with rank, as women comprise 46% of assistant professors, 34% of associate professors, and 19% of full professors. We quantify the attrition of women in terms of a fractionation factor, which describes the rate of loss of women along the tenure track and allows us to move away from the metaphor of the ‘leaky pipeline’. Efforts to address inequities in institutional culture and biases in promotion and hiring practices over the past few years may provide insight into the recent positive shifts in fractionation factor. Our results suggest a need for 1:1 hiring between men and women to reach gender parity. Due to significant disparities in race, this work is most applicable to white women, and our use of the gender binary does not represent gender diversity in the geosciences.

The Ediacaran-aged Shuram excursion was the last and largest of the Neoproterozoic negative carbon isotope anomalies. Recognized in stratigraphic successions around the globe, it precedes diverse evidence for macroscopic, multicellular life, and follows the Cryogenian global glaciations and Ediacaran Gaskiers glaciation. Hypotheses for the cause of the Shuram excursion can be broadly grouped into those that argue for post-depositional diagenetic alteration of the carbon isotope record and those that argue the extremely low δ13C values reflect a primary perturbation to the carbon cycle. Given the timing and magnitude of this event, distinguishing between these disparate hypotheses, or combining them, is critical for reconstructing the environmental conditions under which complex life evolved on Earth. We test specific predictions of each model using a range of stratigraphic observations and micro- and macro-analytical techniques. We find that the type sections in Oman where the Shuram excursion was first described are well preserved and contain a range of features difficult to reconcile with a post-depositional origin. However, many salient features are consistent with an extreme warming event coupled to a carbon cycle perturbation, analogous to the Paleocene-Eocene Thermal Maximum (PETM), and increased middle Ediacaran volcanism. We propose that cooling associated with the recovery was critical for origination rates of macroscopic soft-bodied organisms.

The habitability and ecology of Earth is fundamentally shaped by surface temperature, but the temperature history of our planet is not easily reconstructed, especially before the evolution of early biomineralizing animals. This work presents a billion-year-long, high-resolution, mineral-specific record of oxygen isotope measurements in shallow marine rocks. Clumped isotope paleothermometry results from four minerals resolves previous ambiguity in seawater oxygen isotope composition and confirms that long-term cooling punctuated by short-lived temperature extremes are dominant components of this record. We consider post-depositional effects by comparing Phanerozoic rock and fossil records, and identify temporal and spatial controls on alteration. Furthermore, this record is suggestive of key differences in dolomite (CaMg(CO3)2) formation processes between the Neoproterozoic (1000–538.8 Ma) and Phanerozoic (538.8–0 Ma), consistent with previous suggestions based on petrographic and sedimentological observations. This record, when viewed alongside the fossil record, suggests temperature change is tightly coupled to extinction and origination in the history of life and carbon cycle perturbations over the last billion years.

Quantitative scanning electron microscopy (SEM) quartz microtextural analysis can reveal the transport histories of modern and ancient sediments. However, because workers identify and count microtextures differently, it is difficult to directly compare quantitative microtextural data analyzed by different workers. As a result, the defining microtextures of certain transport modes and their probabilities of occurrence are not well constrained. We used principal component analysis (PCA) to directly compare modern and ancient aeolian, fluvial, and glacial samples from the literature with 9 new samples from active aeolian and glacial environments. Our results demonstrate that PCA can group microtextural samples by transport mode and differentiate between aeolian and fluvial/glacial transport modes across studies. The PCA ordination indicates that aeolian samples are distinct from fluvial and glacial samples, which are in turn difficult to disambiguate from each other. Ancient and modern sediments are also shown to have quantitatively similar microtextural relationships. Therefore, PCA may be a useful tool to constrain the ambiguous transport histories of some ancient sediment grains. As a case study, we analyzed two samples with ambiguous transport histories from the Cryogenian Bråvika Member (Svalbard). Integrating PCA with field observations, we find evidence that the Bråvika Member facies investigated here includes aeolian deposition and may be analogous to syn-glacial Marinoan aeolian units including the Bakoye Formation in Mali and the Whyalla Sandstone in South Australia.

Carbonate rocks on continental crust are one of Earth’s largest reservoirs of CO2 and yet the controls on their volume through time are poorly understood. Here we quantify temporal changes in preserved continental carbonate rocks over the last billion years in both global and North America-specific datasets within paleogeographic context. We find the preserved area of continental carbonate rocks increases by ~175% across the Neoproterozoic-Phanerozoic boundary ca. 539 million years ago, coincident with the rise of macroscopic, multicellular life and the evolutionary innovation of carbonate biomineralization in shallow water reefs. We demonstrate that crustal loading from carbonate sediments on one tropical paleo-continent (North America) contributes to an increase in continent-scale accommodation in the early Phanerozoic, expanding shallow marine environments. We predict this feedback between enhanced carbonate accumulation and subsidence was an important component of the termination of the Great Unconformity. These results are combined into a new conceptual model that links the changes in preserved carbonate rock volumes to the evolutionary innovation of carbonate biomineralization in a range of complex organisms. Our model implies evolutionary controls on the carbonate rock reservoir enhanced CO2 sequestration at the beginning of the Phanerozoic, with consequences for Earth’s carbon cycle, climate and habitability.