The term “ionospheric sluggishness” is used to describe the time delay between maximum radio absorption in the ionosphere following the time of maximum irradiance during a solar flare. Sluggishness is one of the characteristic properties known to be maximized around D-region heights and can be used for studying lower ionospheric (D-region) and mesospheric chemistry. This article is our first attempt to estimate ionospheric sluggishness using high frequency (HF, 3 – 30 MHz) instruments. Specifically, we report on first estimates of sluggishness from riometer and SuperDARN observations following a solar flare and propose two new methods to estimate sluggishness. Sluggishness is shown to be anti-correlated with the peak solar X-ray flux and positively correlated with solar zenith angle and geographic latitude. The choice of instrument, method, and reference solar waveband effects the sluggishness estimation. A simulation study was performed to estimate the effective recombination coefficient, which was found to vary between 4-5 orders of magnitude. We suggest that the effective recombination coefficient is highly sensitive to D-region’s negative and positive ion chemistry.